Wednesday, September 15, 2010

Research on polymer


In my previous post, i talked about polymer and balloons. I do not know much about it except preventing balloon's from bursting so here's my research on polymer:

A polymer is a large molecule(macromolecule) composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a wide variety of properties.

Because of the extraordinary range of properties of polymeric materials, they play an essential and ubiquitous role in everyday life, ranging from familiar synthetic plastics and elastomers to natural biopolymers such as DNA and proteins that are essential for life. A simple example is polyethylene, whose repeating unit is based on ethylene (IUPAC name ethene) monomer. Most commonly, as in this example, the continuously linked backbone of a polymer used for the preparation of plastics consists mainly of carbon atoms. However, other structures do exist; for example, elements such as silicon form familiar materials such as silicones, examples being silly putty and waterproof plumbing sealant. The backbone of DNA is in fact based on a phosphodiester bond, and repeating units of polysaccharides (e.g. cellulose) are joined together by glycosidic bonds via oxygen atoms.

Natural polymeric materials such as shellac, amber, and natural rubber have been used for centuries. Biopolymers such as proteins and nucleic acids play crucial roles in biological processes. A variety of other natural polymers exist, such as cellulose, which is the main constituent of wood and paper.

The list of synthetic polymers includes synthetic rubber, Bakelite, neoprene, nylon, PVC, polystyrene, polyethylene, polypropylene, polyacrylonitrile, PVB, silicone, and many more.

Polymerization is the process of combining many small molecules known as monomers into a covalently bonded chain. During the polymerization process, some chemical groups may be lost from each monomer. This is the case, for example, in the polymerization of PET polyester. The monomers are terephthalic acid (HOOC-C6H4-COOH) and ethylene glycol (HO-CH2-CH2-OH) but the repeating unit is -OC-C6H4-COO-CH2-CH2-O-, which corresponds to the combination of the two monomers with the loss of two water molecules. The distinct piece of each monomer that is incorporated into the polymer is known as a repeat unit or monomer residue.

Polymers are studied in the fields of polymer chemistry, polymer physics, and polymer science.

The word polymer is derived from the Greek words πολυ- - poly- meaning "many"; and μέρος - meros meaning "part". The term was coined in 1833 by Jöns Jacob Berzelius, although his definition of a polymer was quite different from the modern definition.

Wow! I certainly did not know polymer was such an interesting molecule and had so much history!

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